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Explore tandem mass tags (TMT) for isobaric labelling for relative proteomics analysis that provides multiplexing capabilities by the ability to perform 

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Buy Sigma Aldrich 34851-4X4L Acetonitrile for HPLC, Gradient Grade, ≥99.9% (Case of 4 x 4L Bottles)

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It's very likely reliable sample tracking is one of the main reasons you're considering upgrading to a barcode identification system—if not the sole reason.

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